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Acetonitrile → 4-(2,2-dimethylpropyl)-2-methyl-1H-imidazol-1-ol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Acetonitrile | HCID 6342 | — |
| 反応物 | 4,4-Dimethylpent-1-ene | HCID 12984 | — |
| 反応物 | Nitrilooxonium tetrafluoroborate | HCID 11137142 | — |
| 生成物 | 4-(2,2-dimethylpropyl)-2-methyl-1H-imidazol-1-ol | HCID 68667641 | — |
反応手順
4,4-Dimethyl-1-pentene (59 g, 0.6 mol) was added to a 10° C. suspension of nitrosonium tetrafluoroborate (66 g, 0.56 mmol) in acetonitrile (600 mL) After stirring vigorously at ambient temperature for 30 minutes, acetonitrile was removed in vacuo to afford 4-(2,2-dimethylpropyl)-2-methyl-1H-imidazol-1-ol which was used in the subsequent step without further purification.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08193228B2 |
| 出典データセット | uspto-grants-2012_06 |
| ORD ID | ord-8f275411a5eb43a3b0991880d70309c4 |
| 出典メモ | uspto-grants-2012_06 |