HCID 19812671、化合物 → HCID 19812678、化合物

反応式

[CH3:1][O:2][CH2:3][O:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=1[C:11]([C:13]1[CH:18]=[CH:17][C:16]([CH3:19])=[CH:15][C:14]=1[O:20][CH3:21])=[CH2:12].[C:22]1(SC[Li])C=CC=CC=1>>[CH3:1][O:2][CH2:3][O:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=1[C:11]1([C:13]2[CH:18]=[CH:17][C:16]([CH3:19])=[CH:15][C:14]=2[O:20][CH3:21])[CH2:22][CH2:12]1

参加物

反応物 2

HCID 19812671HCID 19812671、化合物

HCID 178506884HCID 178506884、化合物

生成物 1

HCID 19812678HCID 19812678、化合物収率 44%

実験手順

The general procedure of Example 34 was followed using 1-(2-methoxymethoxyphenyl)-1-(4-methyl-2-methoxyphenyl)ethene and, initially, 3.3 moles of phenylthiomethyl lithium reagent per mole of olefin. The title compound was obtained as a clear oil in 44 percent yield and its structure was verified by proton NMR spectroscopy.

出典と根拠

ORDレコード: ord-db11e1d1769549419c3740b024ed81c3
出典データセット: uspto-grants-1990_07
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04938790

反応ノート

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