化工社化工社 化学情報印刷レポート · 研究参考用
Ammonia → Allylamine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ammonia | HCID 222 | — |
| 反応物 | Triallylamine | HCID 7617 | — |
| 反応物 | Allyl Alcohol | HCID 7858 | — |
| 反応物 | 1,3-Propanediol | HCID 10442 | — |
| 反応物 | 1,4-Bis(diphenylphosphino)butane | HCID 82124 | — |
| 触媒 | Palladium Chloride | HCID 24290 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | Allylamine | HCID 7853 | — |
| 生成物 | Diallylamine | HCID 31279 | — |
反応手順
To 1.8 mg (0.01 millimole) of PdCl2 was added 8.5 mg (0.02 millimole) of 1,4-bis(diphenylphosphino)butane, and 5.0 g of 1,3-propane-diol and 3.6 g of water were added and reaction between 8.4 g (145 millimoles) of allyl alcohol and 3.2 g (188 millimoles) of ammonia was carried out at 110° C. with stirring for 2 hours. As the products, there were obtained 0.26 g (4.6 millimoles) of monoallylamine, 0.53 g (5.4 millimoles) of diallylamine 0.63 g (4.6 millimoles) of triallylamine. The conversion based on allyl alcohol was 21.5% and the selectivity was 96.8%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04942261 |
| 出典データセット | uspto-grants-1990_07 |
| ORD ID | ord-692e55a0d76041d3a7e1aa34e763b27d |
| 出典メモ | uspto-grants-1990_07 |