化工社化工社 化学情報印刷レポート · 研究参考用
Ammonia → Triallylamine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ammonia | HCID 222 | — |
| 反応物 | Allylamine | HCID 7853 | — |
| 反応物 | Allyl Alcohol | HCID 7858 | — |
| 反応物 | 1,4-Butanediol | HCID 8064 | — |
| 反応物 | 1,4-Bis(dibutylphosphino)butane | HCID 13415111 | — |
| 生成物 | Triallylamine | HCID 7617 | — |
| 生成物 | Diallylamine | HCID 31279 | — |
反応手順
To 12.2 mg (0.04 millimole) of Pd(CH2COCH2COCH3)2 was added 42.6 mg (0.10 millimole) of 1,4-bis(dibutylphosphino)butane, and 5.0 g of 1,4-butane-diol was added and reaction between 8.4 g (182 millimoles) of allyl alcohol and 3.1 g (182 millimoles) of ammonia was carried out at 120° C. for 2 hours with stirring. As the products, there were obtained 0.91 (16.0 millimoles) of monoallylamine, 1.85 g (19.1 millimoles) of diallylamine and 2.35 g (17.2 millimoles) of triallylamine. The conversion based on allylalcohol was 74.3%, and the selectivity was 98.2%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04942261 |
| 出典データセット | uspto-grants-1990_07 |
| ORD ID | ord-9dc78c9411d54f8191a39404f11287cc |
| 出典メモ | uspto-grants-1990_07 |