化工社化工社 化学情報印刷レポート · 研究参考用
Hydrogen Peroxide → 1,2-Epoxycyclooctane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydrogen Peroxide | HCID 784 | — |
| 反応物 | Chloroform | HCID 6212 | — |
| 反応物 | 1-Cyclooctene | HCID 13609 | — |
| 反応物 | 2-Propanone, 1,1,1,3-tetrachloro- | HCID 28188 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | 1,2-Epoxycyclooctane | HCID 67513 | 83% |
反応手順
There were added 13.68 parts of a 50% aqueous hydrogen peroxide to a refluxing mixture of 3.92 parts of tetrachloroacetone, 11.58 parts of cyclooctene and 149 parts of chloroform. Water was removed continuously as it was formed, over a period of 4 hours of heating. The removed water was then added to the reaction mixture. The organic phase was then separated from the aqueous phase. Based on VPC analysis is there was obtained an 83% yield of cyclooctene oxide.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04389529 |
| 出典データセット | uspto-grants-1983_06 |
| ORD ID | ord-4325ce9dd96c484c9bfa7f553a421349 |
| 出典メモ | uspto-grants-1983_06 |