2-Hydroxy-4-methoxybenzophenone → 2,2'-Dihydroxy-4-methoxybenzophenone

HRID 2167113

反応式

HRID 2167113 の反応式
OC1C=C(O)C=CC=1C(C1C=CC(O)=CC=1O)=O.OC1C=C(OC)C=CC=1C(C1C=CC=CC=1)=O.[OH:36][C:37]1[CH:53]=[C:52](OC)[CH:51]=[CH:50][C:38]=1[C:39]([C:41]1[CH:46]=[CH:45][C:44]([O:47][CH3:48])=[CH:43][C:42]=1[OH:49])=[O:40].COC1C=C(O)C(C(C2C(O)=CC(OC)=C(S([O-])(=O)=O)C=2)=O)=CC=1S([O-])(=O)=O.[Na+].[Na+].OC1C(C(=O)C2C=CC=CC=2)=CC(S(O)(=O)=O)=C(OC)C=1.NC1C=CC=CC=1C(C1C=CC=CC=1)=O>>[OH:49][C:42]1[CH:43]=[C:44]([O:47][CH3:48])[CH:45]=[CH:46][C:41]=1[C:39]([C:38]1[CH:50]=[CH:51][CH:52]=[CH:53][C:37]=1[OH:36])=[O:40]

参加物

7

反応物 6

HCID 46322-Hydroxy-4-methoxybenzophenoneHCID 8570Benzophenone-6HCID 85712,2',4,4'-TetrahydroxybenzophenoneHCID 19988SulisobenzoneHCID 760802-AminobenzophenoneHCID 154926Benzophenone-9

生成物 1

HCID 85692,2'-Dihydroxy-4-methoxybenzophenone

実験手順

2,2′,4,4′-tetrahydroxybenzophenone (benzophenone-2, Uvinul® D-50); 2-hydroxy-4-methoxybenzophenone (oxybenzone, benzophenone-3); 2,2′-dihydroxy-4,4′-dimethoxybenzophenone (benzophenone-6); 2,2′-dihydroxy-4,4′-dimethoxybenzophenone-5,5′-disulphonic acid sodium salt (benzophenone-9); 4-hydroxy-2-methoxy-5-(oxo-phenylmethyl)benzenesulfonic acid (sulisobenzone, benzophenone-4); 2-hydroxy-4-methoxybenzophenone-5-sulphonic acid sodium salt (benzophenone-5), 2-aminobenzophenone;

出典と根拠

ORDレコード
ord-e4a05549dad44904bf4f9ea90267e1a1
出典データセット
uspto-grants-2015_06
特許番号
US09044623B2

関連ノート

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