化工社化工社 化学情報印刷レポート · 研究参考用
Toluene → N'-t-butyl-N-pyrenonecarbonyl-N'-(3-toluoyl)hydrazine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Toluene | HCID 1140 | — |
| 反応物 | Diethyl Ether | HCID 3283 | — |
| 反応物 | Hexane | HCID 8058 | — |
| 反応物 | tert-Butylhydrazine monohydrochloride | HCID 81889 | — |
| 反応物 | Pyrenonecarbonyl chloride | HCID 131717420 | — |
| 溶媒 | Hydroxide | HCID 961 | — |
| 生成物 | N'-t-butyl-N-pyrenonecarbonyl-N'-(3-toluoyl)hydrazine | HCID 131717419 | — |
反応手順
To a stirred suspension of t-butyl hydrazine hydrochloride (0.02 mol) in toluene (20 ml) and aqueous hydroxide (5 ml of 50% solution) at room temperature was added pyrenonecarbonyl chloride (0.01 mol). After stirring the reaction mixture for 20 minutes, ether and hexane were added and the solid product was filtered and washed with water. The solid product (0.5 g) was stirred in toluene (10 ml) and aqueous sodium hydroxide and m-toluoyl chloride (0.8 g) was added dropwise. After stirring for 5 hours, hexane and ether were added and the solid product filtered and air dried.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05424333 |
| 出典データセット | uspto-grants-1995_06 |
| ORD ID | ord-4ace12a6e29447b3bbd6b021605bd28a |
| 出典メモ | uspto-grants-1995_06 |