Carbon Dioxide → Carbon Dioxide

HRID 2168859ノート

反応式

HRID 2168859 の反応式
[CH3:1][CH:2]1[CH2:6][CH2:5][CH2:4][O:3]1.[C:7](=[O:9])=[O:8]>[Zn].[Mg]>[C:7](=[O:3])([OH:9])[OH:8].[CH2:4]([OH:3])[CH2:5][CH2:6][CH:2]([OH:8])[CH3:1].[CH3:1][CH:2]1[CH2:6][CH2:5][CH2:4][O:3]1.[C:4](=[O:3])=[O:8]

参加物

6

反応物 2

HCID 280Carbon Dioxide2 回HCID 73012-Methyltetrahydrofuran2 回

生成物 3

HCID 280Carbon DioxideHCID 73012-MethyltetrahydrofuranHCID 867022981,4-Pentanediol carbonate

試薬・触媒・溶媒 1

HCID 11457656Magnesium--zinc (1/1)触媒

実験手順

Adding 2-methyl tetrahydrofuran prepared by the embodiment 3 and the magnesium-zinc-rare earth oxide composite catalyst into a reactor at the weight ratio of 100:1; opening a heating device to keep temperature of the rector constant at 80° C.; filling excessive CO2 into the reactor, and controlling the absolute pressure in the reactor under 6.0 MPa; performing a cycloaddition reaction between 2-methyl tetrahydrofuran and CO2 in the reactor for 20 minutes to obtain the reaction product, distilling the reaction product to obtain 1,4-pentanediol carbonate, wherein the mole ratio of 2-methyl tetrahydrofuran to CO2 is 1:15, conversion rate of 2-methyl tetrahydrofuran in the cycloaddition reaction is 86%, and yield of 1,4-pentanediol carbonate is 54%.

後処理

  1. customprepared by the embodiment 3
  2. customconstant at 80° C.
  3. customto obtain the reaction product
  4. distillationdistilling the reaction product

出典と根拠

ORDレコード
ord-c9bab6c16bbd4dff9afe7326e08ad81d
出典データセット
uspto-grants-2015_06
特許番号
US09045707B2

反応ノート

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