Cyclopropanol → Cyclopropanol

HRID 2168862ノート

反応式

HRID 2168862 の反応式
[C:1](=[O:4])([OH:3])[OH:2].[CH2:5]([OH:11])[CH2:6][CH2:7][CH:8]([OH:10])[CH3:9].[CH:12]1([OH:15])[CH2:14][CH2:13]1>>[C:1](=[O:2])([OH:4])[OH:3].[CH:8]1([OH:10])[CH2:9][CH2:7]1.[CH:12]1([OH:15])[CH2:14][CH2:13]1.[C:1](=[O:2])([OH:4])[OH:3].[CH2:5]([OH:11])[CH2:6][CH2:7][CH:8]([OH:10])[CH3:9].[CH:1]1([OH:4])[CH2:6][CH2:5]1

参加物

5

反応物 2

HCID 123361CyclopropanolHCID 867022981,4-Pentanediol carbonate

生成物 3

HCID 123361CyclopropanolHCID 71346270Carbonic acid--cyclopropanol (1/2)HCID 867022981,4-Pentanediol carbonate

実験手順

Adding 1,4-pentanediol carbonate and cyclopropanol in a tubular ester exchange reactor; then adding the metal-rare earth oxide composite catalyst prepared by the embodiment 3, uniformly mixing and performing an ester exchange reaction, distilling the reaction product to obtain dicyclopropanol carbonate, wherein the mole ratio of 1,4-pentanediol carbonate to cyclopropanol is 1:15, and the weight ratio of the metal-rare earth oxide composite catalyst to the total weight of 1,4-pentanediol carbonate and cyclopropanol is 2:100; the ester exchange reaction is performed at a temperature of 140° C. and under an absolute pressure of 0.5 MPa for 120 minutes; in the ester exchange reaction, the conversion rate of 1,4-pentanediol carbonate is 99%, and yield of the dicyclopropanol carbonate is 93%.

後処理

  1. customprepared by the embodiment 3
  2. additionuniformly mixing
  3. distillationdistilling the reaction product

出典と根拠

ORDレコード
ord-827e696940a94fc4bf834d33b7cc0bc7
出典データセット
uspto-grants-2015_06
特許番号
US09045707B2

反応ノート

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