Carbon Dioxide → 2-(prop-2-yn-1-yl)pent-4-ynoic acid
反応式
[CH2:1]([C:4]([CH2:11][C:12]#[CH:13])(C(O)=O)[C:5]([OH:7])=[O:6])[C:2]#[CH:3].C(=O)=O>>[CH2:1]([CH:4]([CH2:11][C:12]#[CH:13])[C:5]([OH:7])=[O:6])[C:2]#[CH:3]参加物
3
実験手順
The dipropargylmalonic acid (26 gm, 0.443 mol) was heated neat at 135 C until CO2 stopped evolving. It was then allowed to cool to an oil. The oil was distilled at 0.5 psi. The remaining oily residue in the distillation flask and solid were combined (15.7 gm, 79.9% yield) and was used as is in the next step.
後処理
- temperatureto cool to an oil
- distillationThe oil was distilled at 0.5 psi
出典と根拠
- ORDレコード
- ord-545cf4bbd49e4424a2f28d6a38257435
- 出典データセット
- uspto-grants-2015_06
- 特許番号
- US09050370B2
反応ノート
読み込み中…