2-Bromobenzenethiol → Methyl 3-bromo-6-(2-bromophenylthiomethyl)-2-methoxybenzoate

HRID 2177748ノート

反応式

HRID 2177748 の反応式
BrC1C(OC)=C(C=CC=1CSC1C=CC=CC=1C)C(OCC)=O.[Br:24][C:25]1[C:26]([O:37][CH3:38])=[C:27]([C:32]([CH2:35]Br)=[CH:33][CH:34]=1)[C:28]([O:30][CH3:31])=[O:29].[Br:39][C:40]1[CH:45]=[CH:44][CH:43]=[CH:42][C:41]=1[SH:46]>>[Br:24][C:25]1[C:26]([O:37][CH3:38])=[C:27]([C:32]([CH2:35][S:46][C:41]2[CH:42]=[CH:43][CH:44]=[CH:45][C:40]=2[Br:39])=[CH:33][CH:34]=1)[C:28]([O:30][CH3:31])=[O:29]

参加物

4

反応物 3

HCID 805982-BromobenzenethiolHCID 66685947Methyl 3-bromo-6-bromomethyl-2-methoxybenzoate2 回HCID 67107587Ethyl 3-bromo-2-methoxy-(2-methylphenylthiomethyl)benzoate

生成物 1

HCID 67107621Methyl 3-bromo-6-(2-bromophenylthiomethyl)-2-methoxybenzoate

実験手順

Prepared by proceeding in a similar manner to Intermediate 77, starting from methyl 3-bromo-6-bromomethyl-2-methoxybenzoate (Intermediate 89) and 2-bromothiophenol.

後処理

  1. customPrepared

出典と根拠

ORDレコード
ord-b53d93d32d124a6fb3afd16fbd97a3a3
出典データセット
uspto-grants-2015_06
特許番号
US09067905B2

反応ノート

読み込み中…