Methyl 6-(bicyclo[2.2.1]hept-7-ylthiomethyl)-3-bromo-2-methoxybenzoate → Methyl 6-(bicyclo[2.2.1]heptane-7-ylsulphonylmethyl)-3-bromo-2-methoxybenzoate
反応式
[Br:1][C:2]1[C:3]([O:23][CH3:24])=[C:4]([C:9]([CH2:12][S:13](C2C=CC=CC=2O)(=[O:15])=[O:14])=[CH:10][CH:11]=1)[C:5]([O:7][CH3:8])=[O:6].[CH:25]12[CH:31](SCC3C(C(OC)=O)=C(OC)C(Br)=CC=3)[CH:28]([CH2:29][CH2:30]1)[CH2:27][CH2:26]2>>[CH:25]12[CH:31]([S:13]([CH2:12][C:9]3[C:4]([C:5]([O:7][CH3:8])=[O:6])=[C:3]([O:23][CH3:24])[C:2]([Br:1])=[CH:11][CH:10]=3)(=[O:14])=[O:15])[CH:28]([CH2:29][CH2:30]1)[CH2:27][CH2:26]2参加物
3
実験手順
Prepared by proceeding in a similar manner to Intermediate 138, starting from methyl 6-(bicyclo[2.2.1]heptan-7-ylthiomethyl)-3-bromo-2-methoxybenzoate (Intermediate 182).
後処理
- customPrepared