N-benzylaminosulfonamide → Benzylsulfamide potassium salt

HRID 2189129ノート

反応式

HRID 2189129 の反応式
[CH2:1]([NH:8][S:9]([NH2:12])(=[O:11])=[O:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.CC([O-])(C)C.[K+:18]>>[K+:18].[CH2:1]([NH:8][S:9]([NH-:12])(=[O:11])=[O:10])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

参加物

3

反応物 2

HCID 12354987N-benzylaminosulfonamideHCID 23665647Potassium tert-butoxide

生成物 1

HCID 21041359Benzylsulfamide potassium salt収率 100.6%

実験手順

To a solution of benzylsulfamide (17.98 g) in McOH (300 mL) was carefully added potassium tert-butylate (10.8 g). The mixture was stirred at rt for 15 min before the solvent was evaporated. The remaining residue was dried under HV to give benzylsulfamide potassium salt as an off-white powder (21.73 g).

後処理

  1. customwas evaporated
  2. customThe remaining residue was dried under HV

出典と根拠

ORDレコード
ord-5d1afc6e2d174f638edd86682471e518
出典データセット
uspto-grants-2012_12
特許番号
US08324232B2

反応ノート

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