化工社化工社 化学情報印刷レポート · 研究参考用
Vinyl Acetate → 2-Vinyl-2-azabicyclo[2.2.1]hept-5-en-3-one
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Vinyl Acetate | HCID 7904 | — |
| 反応物 | 2-Azabicyclo(2.2.1)hept-5-en-3-one | HCID 548678 | — |
| 触媒 | HCID 178479786 | HCID 178479786 | — |
| 生成物 | 2-Vinyl-2-azabicyclo[2.2.1]hept-5-en-3-one | HCID 60007647 | — |
反応手順
A solution of 2-azabicyclo[2.2.1]hept-5-en-3-one (0.5 g, 4.6 mmole) in vinyl acetate (3 ml, 33 mmole) with sodium tetrachloropalladate (15 mg, 0.05 mmole) was refluxed for 5 days. The product, Compound 6, was isolated by evaporation of the volatiles. Analysis by Gas Liquid Chromatography-Mass Spectrometry (GLC-MS) was consistent with the predicted molecular weight.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08202833B2 |
| 出典データセット | uspto-grants-2012_06 |
| ORD ID | ord-3865ab6554404ec9b59a3a1abbb6b7da |
| 出典メモ | uspto-grants-2012_06 |