化工社化工社 化学情報印刷レポート · 研究参考用
2-Aminoheptane → 1-sec-heptyl-3-n-hexyl-2-S-ethylisothiourea
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Aminoheptane | HCID 5603 | — |
| 反応物 | Iodoethane | HCID 6340 | — |
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | Hexyl isothiocyanate | HCID 78120 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | 1-sec-heptyl-3-n-hexyl-2-S-ethylisothiourea | HCID 13083466 | — |
反応手順
The equipment, procedure and reactants were the same as in Example 31 with the exception that 10.01 g (0.07 mole) of n-hexylisothiocyanate, 8.05 g (0.07 mole) 2-aminoheptane, 35 ml ethanol 2B, 11.7 g (0.075 mole) ethyl iodide, 200 ml of toluene and a one percent solution sodium hydroxide (0.08 mole) were used as reactants and reagents in the procedure. The reaction produced 19.6 g (98 weight percent of theory yield of a clear liquid having a nD30 of 1.4765. The product was identified as the title product by IR and NMR spectra analyses.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04357351 |
| 出典データセット | uspto-grants-1982_11 |
| ORD ID | ord-83125b7fc31f4b07bc0367c2d27d4ffe |
| 出典メモ | uspto-grants-1982_11 |