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Aniline → N''-Butyl-N,N,N',N'-tetramethyl-guanidine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Aniline | HCID 6115 | — |
| 反応物 | Butylamine | HCID 8007 | — |
| 反応物 | Triethylamine | HCID 8471 | — |
| 反応物 | HCID 178517994 | HCID 178517994 | — |
| 生成物 | N''-Butyl-N,N,N',N'-tetramethyl-guanidine | HCID 525255 | 84% |
反応手順
The procedure of Example 4 was repeated, except that the solution of aniline in TMPG was replaced with a solution of n-butylamine (36.6 g, 0.5 mole) in triethylamine (51 g, 0.5 mole). Workup and distillation, as indicated, yielded 72.0 g (0.42 mole) of N"-butyl-N,N,N',N'-tetramethyl guanidine, bp. 31°-32° C. at 0.03 mm, nD22.3 1.4600, which corresponded to 84% yield of the theory.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04358613 |
| 出典データセット | uspto-grants-1982_11 |
| ORD ID | ord-701a3db9898b42f4a7c46a6c4ff8d200 |
| 出典メモ | uspto-grants-1982_11 |