化工社化工社 化学情報印刷レポート · 研究参考用
Salicyl Alcohol → 2-[(Ethylsulfanyl)methyl]phenol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Salicyl Alcohol | HCID 5146 | — |
| 反応物 | Ethanethiol | HCID 6343 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | 2-[(Ethylsulfanyl)methyl]phenol | HCID 522167 | 95.1% |
反応手順
A mixture of 99.2 g (0.8 mol) of 2-hydroxymethyl-phenol and 124 g (2 mol) of ethylmercaptan was heated for 5 hours to 170° C. in a VA autoclave, whilst stirring. After cooling to room temperature, the unconverted ethylmercaptan and the water of reaction were distilled off under normal pressure, and subsequently the 2-ethylthiomethyl-phenol was distilled off under 1.5 mm Hg. 128 g of 2-ethylthiomethyl-phenol (ca. 95% of theory) were obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04358616 |
| 出典データセット | uspto-grants-1982_11 |
| ORD ID | ord-032b17f7153c419392411b40e010db18 |
| 出典メモ | uspto-grants-1982_11 |