4-Toluenesulfonyl chloride → 9-Tosyloxymethyl-9,10-dihydro-9,10-methanoanthracene

HRID 2198635

反応式

HRID 2198635 の反応式
[OH:1][CH2:2][C:3]12[CH2:17][CH:10]([C:11]3[CH:12]=[CH:13][CH:14]=[CH:15][C:16]=31)[C:9]1[C:4]2=[CH:5][CH:6]=[CH:7][CH:8]=1.[C:18]1([CH3:28])[CH:23]=[CH:22][C:21]([S:24](Cl)(=[O:26])=[O:25])=[CH:20][CH:19]=1>>[S:24]([O:1][CH2:2][C:3]12[CH2:17][CH:10]([C:9]3[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=31)[C:11]1[C:16]2=[CH:15][CH:14]=[CH:13][CH:12]=1)([C:21]1[CH:22]=[CH:23][C:18]([CH3:28])=[CH:19][CH:20]=1)(=[O:26])=[O:25]

参加物

3

反応物 2

HCID 73974-Toluenesulfonyl chlorideHCID 130690829-Hydroxymethyl-9,10-dihydro-9,10-methanoanthracene

生成物 1

HCID 205199599-Tosyloxymethyl-9,10-dihydro-9,10-methanoanthracene

実験手順

9-Tosyloxymethyl-9,10-dihydro-9,10-methanoanthracene is prepared from 9-hydroxymethyl-9,10-dihydro-9,10-methanoanthracene by treatment with p-toluenesulfonyl chloride in the presence of a base in an inert solvent;

出典と根拠

ORDレコード
ord-7919c736ebf44494a99ce60d992c4537
出典データセット
uspto-grants-1982_11
特許番号
US04358620

関連ノート

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