Acetic Acid → 2-Butanone, 2-phenylhydrazone

HRID 220466ノート

反応式

HRID 220466 の反応式
C(O)(=O)C.[C:5]1([NH:11][NH2:12])[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.[CH3:13][C:14](=O)[CH2:15][CH3:16]>C(O)C>[CH3:13]/[C:14](=[N:12]\[NH:11][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)/[CH2:15][CH3:16]

参加物

5

反応物 3

HCID 176Acetic AcidHCID 6569Methyl Ethyl KetoneHCID 7516Phenylhydrazine

生成物 1

HCID 95761802-Butanone, 2-phenylhydrazone

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

Add acetic acid (1.00 mL, 17.45 mmol) and phenyl hydrazine (1.98 mL, 20.00 mmol) to a solution of 2-butanone (2.15 mL, 24.00 mmol) in ethanol (90 mL) at room temperature. Stir the reaction for 1 hr., then remove the solvents in vacuo to give N-[1-methyl-prop-(E)-ylidene]-N′-phenyl-hydrazine as a crude orange oil (3.21 g, 99%). MS (ES): m/z=163 [M+H]+.

後処理

  1. customthe reaction for 1 hr
  2. custom, then remove the solvents in vacuo

出典と根拠

ORDレコード
ord-e02edeb4e209494583a669683f5aa848
出典データセット
uspto-grants-2012_06
特許番号
US08202873B2

反応ノート

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