3,4-(Methylenedioxy)phenylacetonitrile → HCID 71272566、化合物
反応式
[OH:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][O:13][C:14]1[CH:21]=[CH:20][C:17]([CH:18]=O)=[CH:16][CH:15]=1.[CH2:22]1[O:30][C:29]2[CH:28]=[CH:27][C:26]([CH2:31][C:32]#[N:33])=[CH:25][C:24]=2[O:23]1>>[O:30]1[C:29]2[CH:28]=[CH:27][C:26](/[C:31](=[CH:18]/[C:17]3[CH:20]=[CH:21][C:14]([O:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][OH:1])=[CH:15][CH:16]=3)/[C:32]#[N:33])=[CH:25][C:24]=2[O:23][CH2:22]1参加物
3
実験手順
(2Z)-2-(1,3-benzodioxol-5-yl)-3-{4-[(11-hydroxyundecyl)oxy]phenyl}prop-2-enenitrile is prepared starting from 4-[(11-hydroxyundecyl)oxy]benzaldehyde and commercial [3,4-(methylenedioxy)phenyl]acetonitrile according the same procedure following for example 1 in 73% yield. This material proves chromatographically homogenous and displays spectral characteristics consistent with its assigned structure.
出典と根拠
- ORDレコード
- ord-eeccb24abb714c25bbd3ceb12ffd13d9
- 出典データセット
- uspto-grants-2016_06
- 特許番号
- US09366906B2
反応ノート
読み込み中…