Tin tetrachloride → HCID 131735809、化合物
反応式
[CH3:1][C:2]1([C:10]([CH3:12])=[CH2:11])[CH2:7][CH2:6][CH:5]([CH3:8])[CH2:4][C:3]1=[O:9].[CH:13](=[N:17][CH2:18][CH2:19][CH2:20][CH3:21])[CH2:14][CH2:15][CH3:16].Cl[Sn](Cl)(Cl)Cl>ClCCCl>[CH2:13]([N:17]1[CH:18]([CH2:19][CH2:20][CH3:21])[CH2:12][C:10]([CH3:11])=[C:2]([CH3:1])[CH2:7][CH2:6][C@H:5]([CH3:8])[CH2:4][C:3]1=[O:9])[CH2:14][CH2:15][CH3:16]参加物
5
実験手順
Following the general procedure as described in Example 17, 2,5-dimethyl-2-(prop-1-en-2-yl)cyclohexanone (1.06 g, 6.38 mmol), N-butylidenebutan-1-amine (0.97 g, 7.65 mmol), and SnCl4 (1.66 g, 6.38 mmol) in 1,2-dichloroethane (65 ml) were reacted to give the title product as a colorless liquid (1.28 g, 76% yield). 3 isomers in a ratio of 1:2:8.