化工社化工社 化学情報印刷レポート · 研究参考用
Hydrochloric Acid → 2-Propenoic acid, 3-phenyl-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydrochloric Acid | HCID 313 | — |
| 反応物 | 4-Coumaric acid | HCID 322 | — |
| 反応物 | Nitrogen | HCID 947 | — |
| 反応物 | Glycidol | HCID 11164 | — |
| 反応物 | Potassium Hydroxide | HCID 14797 | — |
| 溶媒 | Dimethyl Sulfoxide | HCID 679 | — |
| 溶媒 | Glycerol | HCID 753 | — |
| 生成物 | 2-Propenoic acid, 3-phenyl- | HCID 8784 | — |
反応手順
4.35 g of p-hydroxy cinnamic acid was dissolved in 5 ml of DMSO, and 50 mg of potassium hydroxide was added. The mixture was stirred and heated to 90° C. under flow of N2 gas. 10.0 g of glycidol was added gradually, heating and agitation was carried out for 1.5 hours, neutralized by adding hydrochloric acid and the adduct of cinnamic acid and glycerin was obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05426210 |
| 出典データセット | uspto-grants-1995_06 |
| ORD ID | ord-542a9da6771c4edf9109f3992e977503 |
| 出典メモ | uspto-grants-1995_06 |