化工社化工社 化学情報印刷レポート · 研究参考用
Hydrochloric Acid → 2-Propenoic acid, 3-phenyl-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydrochloric Acid | HCID 313 | — |
| 反応物 | Glycidol | HCID 11164 | — |
| 反応物 | Sodium hydride | HCID 24758 | — |
| 反応物 | Methyl isoferulate | HCID 6439893 | — |
| 溶媒 | Dimethyl Sulfoxide | HCID 679 | — |
| 生成物 | 2-Propenoic acid, 3-phenyl- | HCID 8784 | — |
反応手順
3 g of methyl isoferulate was dissolved in 600 ml of DMSO, and 370 mg of sodium hydride was added. The system was heated to 90° C. under N2 gas flow and 7 g of glycidol was added gradually. Heating and agitation was carried out for 0.5 hours. The system was cooled, neutralized by adding hydrochloric acid, solvent was removed and adduct of cinnamic acid and glycerin was obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05426210 |
| 出典データセット | uspto-grants-1995_06 |
| ORD ID | ord-f297ae3acb9542e7bf85a53dda6a37d2 |
| 出典メモ | uspto-grants-1995_06 |