反応式
[F:1][C:2]([F:37])([C:6]([F:36])([F:35])[C:7]([F:34])([F:33])[C:8]([F:32])([F:31])[C:9]([F:30])([F:29])[C:10]([F:28])([F:27])[C:11]([F:26])([F:25])[C:12]([F:24])([F:23])[C:13]([F:22])([F:21])[C:14]([F:20])([F:19])[C:15]([F:18])([F:17])[F:16])C(O)=O.[Br:38]Br.FF>Cl>[F:1][C:2]([Br:38])([F:37])[C:6]([F:36])([F:35])[C:7]([F:34])([F:33])[C:8]([F:32])([F:31])[C:9]([F:30])([F:29])[C:10]([F:28])([F:27])[C:11]([F:26])([F:25])[C:12]([F:24])([F:23])[C:13]([F:22])([F:21])[C:14]([F:20])([F:19])[C:15]([F:18])([F:17])[F:16]参加物
5
実験手順
Perfluorododecanoic acid 404 g (0.565 mole), bromine 49.4 g (0.309 mole) and Freon 113 (400 ml) were treated with fluorine at 30°-37° C. The reaction mixture was poured into 2N hydrochloric acid (500 ml) and the freon solvent was directly distilled off from the mixture. The residue was cooled and the precipitated solids were collected through known filtration techniques. The precipitate was then distilled under vacuum, to give pure perfluoroundecyl bromide 401 g (95% yield). The bromide has a boiling point of 105° C./2 mm Hg and a melting point of 96°-98° C.
後処理
- distillationthe freon solvent was directly distilled off from the mixture
- temperatureThe residue was cooled
- customthe precipitated solids were collected through known
- filtrationfiltration techniques
- distillationThe precipitate was then distilled under vacuum
出典と根拠
- ORDレコード
- ord-9797e96929ee424e9364cc6c00ff80a4
- 出典データセット
- uspto-grants-1995_10
- 特許番号
- US05455373
関連ノート
読み込み中…