3-Phenylpropyl 4-methylbenzenesulfonate → 5-Cyclohexylpentyl p-toluenesulfonate

HRID 2211076ノート

反応式

HRID 2211076 の反応式
[CH2:1]([CH:11]1[CH2:19][C:18]2[C:13](=[CH:14][CH:15]=[C:16](C3N=CC(O)=CN=3)[CH:17]=2)C1)[CH2:2][CH2:3]CCCCCCC.C(C1C=CC2N=C(C3C=CC(O)=CC=3)SC=2C=1)CCCCCCC.[C:51]1([CH3:70])[CH:56]=[CH:55][C:54]([S:57]([O:60]CCCC2C=CC=CC=2)(=[O:59])=[O:58])=[CH:53][CH:52]=1>>[C:51]1([CH3:70])[CH:52]=[CH:53][C:54]([S:57]([O:60][CH2:3][CH2:2][CH2:1][CH2:11][CH2:19][CH:18]2[CH2:17][CH2:16][CH2:15][CH2:14][CH2:13]2)(=[O:58])=[O:59])=[CH:55][CH:56]=1

参加物

4

反応物 3

HCID 109899213-Phenylpropyl 4-methylbenzenesulfonateHCID 193753532-(2-Decylindan-5-yl)pyrimidine-5-olHCID 1360518844-(6-Octylbenzothiazole-2-yl)phenol

生成物 1

HCID 233615585-Cyclohexylpentyl p-toluenesulfonate収率 62.4%

実験手順

An objective product was prepared in the same manner as in Example 2 except that 2-(2-decylindan-5-yl)pyrimidine-5-ol was changed to 4-(6-octylbenzothiazole-2-yl)phenol and 3-phenylpropyl p-toluenesulfonate was changed to 5-cyclohexylpentyl p-toluenesulfonate (Yield: 62.4%).

出典と根拠

ORDレコード
ord-eda149c5c427407da164cc734ef2e4cb
出典データセット
uspto-grants-1995_10
特許番号
US05462694

反応ノート

読み込み中…