Potassium Iodide → 3-Iodopentafluoropropene-1

HRID 2211196ノート

反応式

HRID 2211196 の反応式
[I-:1].[K+].S(F)(O[C:7]([F:14])([F:13])[C:8]([F:12])=[C:9]([F:11])[F:10])(=O)=O>COCCOCCOCCOCCOC>[F:13][C:7]([I:1])([F:14])[C:8]([F:12])=[C:9]([F:11])[F:10]

参加物

4

反応物 2

HCID 4875Potassium IodideHCID 2776028Pentafluoroallyl fluorosulphate

生成物 1

HCID 27751813-Iodopentafluoropropene-1

試薬・触媒・溶媒 1

HCID 8925Tetraglyme溶媒

反応条件

温度
20 °C

実験手順

Perfluoroallyl iodide (CF2CFCF2I) was prepared by transferring 8.5 g of dry potassium iodide, 20 ml of tetraglyme and 42.5 millimoles of perfluoroallyl fluorosulfate by vacuum line to a 100-ml flask. The mixture was warmed to 20° C. and stirred for 12 hours in a dark room. The mixture was then fractionated through -100° C. and -196° C. traps, with the product being collected in the -100° C. trap.

後処理

  1. customwas then fractionated through -100° C. and -196° C.
  2. customwith the product being collected in the -100° C. trap

出典と根拠

ORDレコード
ord-5394dfafca674a508bd928d8ebb1c478
出典データセット
uspto-grants-1995_10
特許番号
US05463005

反応ノート

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