Sulfolane → 1,1,1,4,4,4-Hexafluoro-2-butene

HRID 2211353

反応式

HRID 2211353 の反応式
Cl[C:2]([F:11])([F:10])[CH:3](Cl)[CH2:4][C:5]([F:8])([F:7])[F:6].C1S(=O)(=O)CCC1.[F-:19].[K+]>>[F:10][C:2]([F:11])([F:19])[CH:3]=[CH:4][C:5]([F:8])([F:7])[F:6]

参加物

4

反応物 3

HCID 31347SulfolaneHCID 522689Potassium FluorideHCID 111174731,2-Dichloro-1,1,4,4,4-pentafluorobutane

生成物 1

HCID 27749751,1,1,4,4,4-Hexafluoro-2-butene収率 89.5%

実験手順

960 g of 1,2-dichloro-1,1,4,4,4-pentafluorobutane were added dropwise to a mixture of 3 1 of distilled tetramethylene sulphone and 830 g of dried potassium fluoride at 190° C. and 1,1,1,4,4,4-hexafluorobut-2-ene was distilled off as it was formed. The product thus obtained was redistilled to give 650 g of 1,1,1,4,4,4-hexafluorobut-2-ene having a boiling point of 8° C at atmospheric pressure.

後処理

  1. distillation1,1,1,4,4,4-hexafluorobut-2-ene was distilled off as it
  2. customwas formed
  3. customThe product thus obtained
  4. distillationwas redistilled

出典と根拠

ORDレコード
ord-459268720f1f4dc699fefbe01e426f9b
出典データセット
uspto-grants-1995_10
特許番号
US05463150

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