Water → Cyclopropanesulphonylbenzene

HRID 2212062ノート

反応式

HRID 2212062 の反応式
[C:1]1([S:7][CH:8]2[CH2:10][CH2:9]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[OH:11]OS([O-])=O.[K+].[OH2:17]>CO>[CH:8]1([S:7]([C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)(=[O:11])=[O:17])[CH2:10][CH2:9]1

参加物

5

反応物 3

HCID 962WaterHCID 123348Cyclopropyl phenyl sulfideHCID 23707502Potassium hydroxy sulfite

生成物 1

HCID 11309899Cyclopropanesulphonylbenzene

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

A solution of cyclopropyl phenyl sulfide (10.5 g, 70 mmol) and Oxone™ (55.13 g, 175 mmol) in methanol (30 ml) was stirred at room temperature for 5 hours. The mixture was diluted was water and extracted with ethyl acetate. The combined organic layers were dried (MgSO4) and concentrated in vacuo.

後処理

  1. additionThe mixture was diluted
  2. extractionextracted with ethyl acetate
  3. dry with materialThe combined organic layers were dried (MgSO4)
  4. concentrationconcentrated in vacuo

出典と根拠

ORDレコード
ord-cf85ed6b24364e7f880c4edaa04925ef
出典データセット
uspto-grants-2006_09
特許番号
US07101892B2

反応ノート

読み込み中…