Carbon Dioxide → 2,3-Diphenylthiophene

HRID 2216729ノート

反応式

HRID 2216729 の反応式
[C:1]1([C:7]2[CH:8]=[C:9](C(O)=O)[S:10][C:11]=2[C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(=O)=O>O>[C:12]1([C:11]2[S:10][CH:9]=[CH:8][C:7]=2[C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=1

参加物

4

反応物 2

HCID 280Carbon DioxideHCID 198352584,5-Diphenylthiophene-2-carboxylic acid

生成物 1

HCID 28017362,3-Diphenylthiophene

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

The 4,5-diphenyl-2-thiophenecarboxylic acid (28 g, 0.1 mol) prepared as described above was heated to 220–230° C. until the evolution of carbon dioxide ceased. The residue was diluted in water and extracted with 100 mL of benzene. The organic phase was dried over MgSO4 and evaporated off to give the crystallized product. Yield 22.45 g (95%).

後処理

  1. extractionextracted with 100 mL of benzene
  2. dry with materialThe organic phase was dried over MgSO4
  3. customevaporated off
  4. customto give the crystallized product

出典と根拠

ORDレコード
ord-ec61541dea7d42e69cc00976658599af
出典データセット
uspto-grants-2006_09
特許番号
US07112638B2

反応ノート

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