Bromoethene → HCID 68938678、化合物

反応式

[CH2:1]=[C:2]1[C:11]2[CH:12]=[CH:13][CH:14]=[CH:15][C:10]=2[CH2:9][CH2:8][C:7]2[S:6][CH:5]=[CH:4][C:3]1=2.C(Br)=C.[NH2:19][C:20]1[CH:21]=[C:22](B(O)O)[CH:23]=[CH:24][CH:25]=1>>[S:6]1[C:7]2[CH2:8][CH2:9][C:10]3[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=3[C:2](=[CH:1][C:24]3[CH:25]=[C:20]([NH2:19])[CH:21]=[CH:22][CH:23]=3)[C:3]=2[CH:4]=[CH:5]1

参加物

反応物 3

HCID 11641Bromoethene2 回

HCID 922693-Aminophenylboronic acid

HCID 597699819,10-Dihydro-4-methylene-4H-benzo[4,5]cyclohepta[1,2-b]thiophene

生成物 1

HCID 68938678HCID 68938678、化合物

実験手順

4-Methylene-9,10-dihydro-4H-1-thia-benzo[f]azulene is converted to the vinyl bromide as in Preparation 24 and the vinyl bromide coupled with 3-aminophenylboronic acid using the procedures essentially as described in Example 219.

出典と根拠

ORDレコード: ord-e581ed6f607d4e3f8a1addfaf5d6cbff
出典データセット: uspto-grants-2008_08
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07411072B2

反応ノート

読み込み中…