Toluene → 4-Ethenylphenyl acetate
反応式
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][O:7][C:8]([C:10](C#N)=C)=[O:9].[C:14]1(C)C=CC=C[CH:15]=1>>[C:8]([O:7][C:6]1[CH:1]=[CH:2][C:3]([CH:14]=[CH2:15])=[CH:4][CH:5]=1)(=[O:9])[CH3:10]参加物
3
実験手順
The purpose of this prophetic Example is to demonstrate the chemical derivatization of pHS in the organic extractant from the biphasic reaction medium to form the derivatized compound para-acetoxystyrene. The pHCA is first produced by fermentation using a recombinant strain of E. coli. The bio-produced pHCA is then converted to pHS in a biphasic reaction medium, consisting of fermentation supernatant and toluene, using PDC2 cell-free extract. After the toluene layer is separated from the pHCA-depleted fermentation supernatant, the bio-produced pHS is reacted with acetic anhydride to form para-acetoxystyrene.
後処理
- customAfter the toluene layer is separated from the pHCA-
- customthe bio-produced pHS is reacted with acetic anhydride
出典と根拠
- ORDレコード
- ord-dff2b47feb3c4ab1b6f4db3e06f878f1
- 出典データセット
- uspto-grants-2008_05
- 特許番号
- US07378261B2
反応ノート
読み込み中…