1-(9-Azabicyclo[4.2.1]non-2-en-2-yl)ethanone → HCID 86748134、化合物
反応式
[CH3:1][N:2]1[CH:8]2[CH2:9][CH2:10][CH:3]1[CH:4](C(=O)C)[CH2:5][CH2:6][CH2:7]2.[C:14](C1C2NC(CCC=1)CC2)(=[O:16])C.C[N:27]1C2CCC1C(C(=O)C)CC2>>[CH3:14][O:16][N:27]=[C:7]1[CH2:6][CH2:5][CH2:4][CH:10]2[CH2:9][CH:8]1[N:2]([CH3:1])[CH2:3]2参加物
4
実験手順
Similarly when N-methyl-2-acetyl-9-azabicyclo[4.2.1]nonane, which can be prepared from 2-acetyl-9-azabicyclo[4.2.1]non-2-ene which is commercially available, is substituted for N-methyl-2-acetyl-8-azabicyclo[3.2.1]octane, compound (5), N-methyl-8-azabicyclo[4.2.1]nonan-2-one methyl oxime is obtained.
出典と根拠
- ORDレコード
- ord-ce765784ef564d11b07ef45e92d48c28
- 出典データセット
- uspto-grants-1994_09
- 特許番号
- US05346911
反応ノート
読み込み中…