Nitrogen → S-[3-(Triethoxysilyl)propyl] ethanethioate

HRID 2227620

反応式

HRID 2227620 の反応式
N#N.[O-:3][CH2:4][CH3:5].[Na+].[S:7]1[CH:11]=[CH:10][CH:9]=C1CC(O)=O.ClCCC[Si:20]([O:27][CH2:28][CH3:29])([O:24][CH2:25][CH3:26])[O:21][CH2:22][CH3:23]>S1C=CC=C1C(O)=O.C(O)C>[C:4]([S:7][CH2:11][CH2:10][CH2:9][Si:20]([O:27][CH2:28][CH3:29])([O:24][CH2:25][CH3:26])[O:21][CH2:22][CH3:23])(=[O:3])[CH3:5]

参加物

7

反応物 4

HCID 947NitrogenHCID 159702-Thiopheneacetic acidHCID 78771(3-Chloropropyl)triethoxysilaneHCID 2723922Sodium ethoxide

生成物 1

HCID 21922028S-[3-(Triethoxysilyl)propyl] ethanethioate収率 78%

試薬・触媒・溶媒 2

HCID 702Ethanol溶媒HCID 107002-Thiophenecarboxylic acid溶媒

実験手順

This example illustrates the preparation of a thiocarboxylate alkoxysilane from a salt of a thiolcarboxylic acid using as a solvent the alcohol corresponding to the silane alkoxy group. Into a 250 ml, 3 neck round bottomed flask equipped with magnetic stir bar, temperature probe/controller, heating mantle, addition funnel, condenser, and N2 inlet was charged 63 grams of a 21 weight percent sodium ethoxide in ethanol. 15 grams of thiolacetic acid was added slowly, keeping the temperature below 65° C. The solution was allowed to cool to room temperature, and 48 grams of chloropropyltriethoxysilane was added via the addition funnel. After addition was complete, the solution was heated to 70° C. for 24 hours whereupon a white solid formed. Analysis of the solution by gas chromatography showed a 78 percent yield of acetylthiopropyltriethoxysilane.

後処理

  1. customInto a 250 ml, 3 neck round bottomed flask equipped with magnetic stir bar
  2. temperaturetemperature probe/controller, heating
  3. customthe temperature below 65° C
  4. additionAfter addition
  5. temperaturethe solution was heated to 70° C. for 24 hours whereupon a white solid
  6. customformed

出典と根拠

ORDレコード
ord-588dc4527c1d4367a8ee84d66e1647fb
出典データセット
uspto-grants-2002_07
特許番号
US06414061B1

関連ノート

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