P-Anisidine → (4-Methoxy-phenyl)-(2-methyl-6-nitro-phenyl)amine
反応式
F[C:2]1[C:7]([CH3:8])=[CH:6][CH:5]=[CH:4][C:3]=1[N+:9]([O-:11])=[O:10].[CH3:12][O:13][C:14]1[CH:20]=[CH:19][C:17]([NH2:18])=[CH:16][CH:15]=1.C([O-])(C)(C)C.[K+]>CS(C)=O>[CH3:12][O:13][C:14]1[CH:20]=[CH:19][C:17]([NH:18][C:2]2[C:3]([N+:9]([O-:11])=[O:10])=[CH:4][CH:5]=[CH:6][C:7]=2[CH3:8])=[CH:16][CH:15]=1参加物
5
実験手順
The product (487 mg) is obtained according to the method of stage 1 of Example 4, by using 1 g of 2-fluoro-3-methyl-nitrobenzene and 1.19 g of 4-methoxyaniline in the presence of 1.16 g of potassium tert-butanolate in 9 mL of DMSO.
出典と根拠
- ORDレコード
- ord-9209797cbcbf4d25bd8c9c78cc271804
- 出典データセット
- uspto-grants-2012_06
- 特許番号
- US08207373B2
反応ノート
読み込み中…