4-Bromoaniline → N-(4-bromophenyl)-2-nitroaniline
反応式
F[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[N+:8]([O-:10])=[O:9].[Br:11][C:12]1[CH:18]=[CH:17][C:15]([NH2:16])=[CH:14][CH:13]=1.C([O-])(C)(C)C.[K+]>CS(C)=O>[Br:11][C:12]1[CH:18]=[CH:17][C:15]([NH:16][C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=2[N+:8]([O-:10])=[O:9])=[CH:14][CH:13]=1参加物
5
実験手順
The product (6.49 g) is obtained according to the method of stage 1 of Example 4, by using 3.73 mL of 2-fluoro-nitrobenzene and 7.31 g of 4-bromoaniline in the presence of 6.36 g of potassium tert-butanolate in 120 mL of DMSO.
出典と根拠
- ORDレコード
- ord-ff8b1bc6869c4847892cf242936975a7
- 出典データセット
- uspto-grants-2012_06
- 特許番号
- US08207373B2
反応ノート
読み込み中…