Triethylamine → N-(cyclohexyl)-1,1-dimethyl-1-(1,5,6,7-tetrahydro-2-methyl-3-phenyl-s-indacen-1-yl)silanamine

HRID 2229750ノート

反応式

HRID 2229750 の反応式
Cl[Si:2]([CH3:23])([CH3:22])[CH:3]1[C:14]2[C:6](=[CH:7][C:8]3[CH2:9][CH2:10][CH2:11][C:12]=3[CH:13]=2)[C:5]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[C:4]1[CH3:21].CCN(CC)CC.C[SiH]([N:34](C1C2C(=C(C)C=C(C)C=2)C(C)=C1C)[CH:35]1[CH2:40][CH2:39][CH2:38][CH2:37][CH2:36]1)C>CCCCCC>[CH:35]1([NH:34][Si:2]([CH3:23])([CH3:22])[CH:3]2[C:14]3[C:6](=[CH:7][C:8]4[CH2:9][CH2:10][CH2:11][C:12]=4[CH:13]=3)[C:5]([C:15]3[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=3)=[C:4]2[CH3:21])[CH2:40][CH2:39][CH2:38][CH2:37][CH2:36]1

参加物

5

反応物 3

HCID 8471TriethylamineHCID 19350461Chlorodimethyl(1,5,6,7-tetrahydro-2-methyl-3-phenyl-s-indacen-1-yl) silaneHCID 131723404HCID 131723404、化合物

生成物 1

HCID 18468905N-(cyclohexyl)-1,1-dimethyl-1-(1,5,6,7-tetrahydro-2-methyl-3-phenyl-s-indacen-1-yl)silanamine収率 89.9%

試薬・触媒・溶媒 1

HCID 8058Hexane溶媒

実験手順

Chlorodimethyl(1,5,6,7-tetrahydro-2-methyl-3-phenyl-s-indacen-1-yl) silane (9c)) (5.6340 g, 0.01633 moles) was stirred in hexane (100 mL) as NEt3 (2.9673 g, 0.02932 moles) and cyclohexylamine (1.6373 g, 0.01651 moles) were added. This mixture was allowed to stir for 24 hours. After the reaction period the mixture was filtered and the volatiles removed resulting in the isolation of the desired product as a yellow oil (5.8969 g, 89.9 percent).

後処理

  1. additionwere added
  2. customAfter the reaction period the mixture
  3. filtrationwas filtered
  4. customthe volatiles removed

出典と根拠

ORDレコード
ord-09c3d9ef3a8e4a8595e9076650fef929
出典データセット
uspto-grants-2002_07
特許番号
US06420507B1

反応ノート

読み込み中…