Cypermethrin → Acrylic Acid

HRID 2231620

反応式

HRID 2231620 の反応式
C[C:2]1(C)[CH:4]([C:5]([O:7][CH:8]([C:11]2[CH:12]=[CH:13][CH:14]=[C:15](OC3C=CC=CC=3)[CH:16]=2)C#N)=[O:6])[CH:3]1C=C(Cl)Cl.[C:29]([O:34][CH2:35][CH2:36][O:37][C:38](=[O:42])[C:39]([CH3:41])=[CH2:40])(=[O:33])[C:30]([CH3:32])=[CH2:31].CCCCCCCCCC1C=CC(OCCOCCOCCOCCOS([O-])(=O)=O)=CC=1.[NH4+]>>[CH2:12]([CH:11]([CH2:16][CH2:15][CH2:14][CH3:13])[CH2:8][O:7][C:5](=[O:6])[CH:4]=[CH2:2])[CH3:29].[C:29]([O:34][CH2:35][CH3:36])(=[O:33])[CH:30]=[CH2:31].[C:5]([OH:7])(=[O:6])[CH:4]=[CH2:3].[C:29]([O:34][CH2:35][CH2:36][O:37][C:38](=[O:42])[C:39]([CH3:41])=[CH2:40])(=[O:33])[C:30]([CH3:32])=[CH2:31]

参加物

7

反応物 3

HCID 2912CypermethrinHCID 7355Ethylene glycol dimethacrylateHCID 24778Polyethylene glycol nonylphenyl ether sulfate ammonium salt

生成物 4

HCID 6581Acrylic AcidHCID 7355Ethylene glycol dimethacrylateHCID 76362-Ethylhexyl acrylateHCID 8821Ethyl Acrylate

実験手順

Example 2 was repeated, except that 29.89 g (4.97 pph) of cypermethrin, 3.00 g (0.50 pph) of ethylene glycol dimethacrylate, and 47.36 g (2.36 pph) of Alipal EP-110 were employed in the monomer premix in lieu of the amounts recited in Example 2. The total batch of about 2658 g provided an aqueous emulsion of the terpolymer of 2-ethylhexylacrylate (62.2 mole %), ethyl acrylate (30.4 mole %) and acrylic acid (7.1 mole %) cross-linked with ethylene glycol dimethacrylate (0.4 mole %) having the ectoparasiticide contained therein. Analysis: theoretical solids, 22.61%; measured solids, 20.4%; 1% of polymer coagulated; conversion (by residual monomers) 99.77%.

後処理

  1. additionpremix in lieu of the amounts

出典と根拠

ORDレコード
ord-8c8c68478a754c0e8edb8b39f081eee8
出典データセット
uspto-grants-1988_11
特許番号
US04783335

関連ノート

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