5-(4-chlorophenoxy)pentan-1-ol → 5-(4-Chlorophenoxy)pentanal

HRID 2232656ノート

反応式

HRID 2232656 の反応式
[Cr](Cl)([O-])(=O)=O.[NH+]1C=CC=CC=1.[Cl:12][C:13]1[CH:25]=[CH:24][C:16]([O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][OH:23])=[CH:15][CH:14]=1>C(Cl)Cl.C(OCC)C>[Cl:12][C:13]1[CH:25]=[CH:24][C:16]([O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH:22]=[O:23])=[CH:15][CH:14]=1

参加物

5

反応物 2

HCID 27948975-(4-chlorophenoxy)pentan-1-olHCID 178418287HCID 178418287、化合物

生成物 1

HCID 232971225-(4-Chlorophenoxy)pentanal

試薬・触媒・溶媒 2

HCID 3283Diethyl Ether溶媒HCID 6344Dichloromethane溶媒

実験手順

To a suspension of 33 g (0.15 mmol) of pyridinium chlorochromate in 450 ml of methylene chloride is added 21.4 g (0.1 mmol) of 5-(4-chlorophenoxy)-1-pentanol. The mixture is maintained with stirring for 3 hours, diluted with 900 ml of ethyl ether and stirred for an additional 1 hour.

後処理

  1. temperatureThe mixture is maintained
  2. stirringstirred for an additional 1 hour

出典と根拠

ORDレコード
ord-0c183e1a097e40549cbce9bafb24be26
出典データセット
uspto-grants-1988_11
特許番号
US04788306

反応ノート

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