関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Vinyl Acetate | HCID 7904 | — |
| 反応物 | Benzenecarbodithioic acid | HCID 67141 | — |
| 溶媒 | Carbon Tetrachloride | HCID 5943 | — |
| 生成物 | 1-Acetoxyethyl dithiobenzoate | HCID 9942835 | 51.5% |
反応手順
A mixture of dithiobenzoic acid (4 g), vinyl acetate (10 mL) and carbon tetrachloride (15 mL) was heated at 70° C. for 16 hours. The resultant mixture was reduced and the residue purified by column chromatography (aluminium oxide column (activity III), n-hexane eluent) to give 1-acetoxyethyl dithiobenzoate (6) (3.21 g, 51.5% yield) as a dark red oil. 1H-nmr (CDCl3) d (ppm): 1.80 (d, 3H); 2.09 (s, 3H); 6.75 (q, 1H); 7.34-7.60 (m, 3H) and 7.97 (m, 2H).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07714075B1 |
|---|
| 出典データセット | uspto-grants-2010_05 |
|---|
| ORD ID | ord-b7cd406a74e549b695a4ade2e0bb10bf |
|---|
| 出典メモ | uspto-grants-2010_05 |
|---|
