Benzylamine → 3-Ethyl-3-n-butyl-12-phenyl-1-aza-1,5,9-cyclododecatriene

HRID 223645

反応式

HRID 223645 の反応式
[CH:1](=[N:8][CH:9]=[C:10]([CH2:15][CH3:16])[CH2:11][CH2:12][CH2:13][CH3:14])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C(N)[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1.[CH2:25](C(=CCCC)C=O)[CH3:26]>>[CH2:11]([C:10]1([CH2:25][CH3:26])[CH2:15][CH:16]=[CH:19][CH2:20][CH2:21][CH:22]=[CH:23][CH2:18][CH:1]([C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)[N:8]=[CH:9]1)[CH2:12][CH2:13][CH3:14]

参加物

4

反応物 3

HCID 7504BenzylamineHCID 125822-Ethylhex-2-EnalHCID 56636874N-benzylidene-(2-ethyl-1-hexenylamine)2 回

生成物 1

HCID 545232413-Ethyl-3-n-butyl-12-phenyl-1-aza-1,5,9-cyclododecatriene

実験手順

The procedure described in Example 1(a) is repeated, except that 215.3 g (1 mol) of N-benzylidene-(2-ethyl-1-hexenylamine) [1-phenyl-4-ethyl-4-n-butyl-2-aza-1,3-butadiene; prepared by reacting benzylamine with 2-ethyl-hexenal and then isomerising the reaction product with potassium tert.-butylate; boiling point 90° C./7 Pa; nD20 =1.5630] are used. Distillation yields 288 g (0.891 mol) of 3-n-butyl-3-ethyl-12-phenyl-1-aza-1,5,9-cyclododecatriene; boiling point 130° C./2 Pa; nD20 =1.5296.

後処理

  1. customprepared
  2. distillationDistillation

出典と根拠

ORDレコード
ord-099217fb9a2d4c969136b0514f5ca373
出典データセット
uspto-grants-1982_10
特許番号
US04355177

関連ノート

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