化工社化工社 化学情報印刷レポート · 研究参考用
Oxygen → Carboxyphenylstearic acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Oxygen | HCID 977 | — |
| 反応物 | Methyl Ethyl Ketone | HCID 6569 | — |
| 反応物 | Butane | HCID 7843 | — |
| 反応物 | 2-(2-Methylphenyl)octadecanoic acid | HCID 22323937 | — |
| 触媒 | Cobalt diacetate | HCID 6277 | — |
| 生成物 | Carboxyphenylstearic acid | HCID 70555697 | 47.9% |
反応手順
The oxidation procedure of Example I was repeated except that only 40 gms cobalt (II) acetate was employed. Also, for this reaction 40 gms methylethyl ketone and 72 gms butane were charged to the reactor. Eighty percent conversion of the tolylstearic acid was achieved after only four hours reaction (105° C. and 350 psig O2). Carboxyphenylstearic acid was obtained in 47.9% yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04356315 |
| 出典データセット | uspto-grants-1982_10 |
| ORD ID | ord-0445cac1340449bb900981407bee45ad |
| 出典メモ | uspto-grants-1982_10 |