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Nitrogen oxide (N2O4) → 3-(4'-Bromophenyl)-2-nitronaphtho-[1,2-b]furan
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Nitrogen oxide (N2O4) | HCID 25352 | — |
| 反応物 | 3-(4'-Bromophenyl)naphtho-[1,2-b]furan | HCID 15571603 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | 3-(4'-Bromophenyl)-2-nitronaphtho-[1,2-b]furan | HCID 15571604 | — |
反応手順
A solution of 2 g. of the product of step B in 50 ml. of dichloromethane is treated with 2.0 g. of dinitrogen tetraoxide, and the mixture is stirred at about 20° C. for about 18 hours. The mixture is evaporated, and the residue obtained is recrystallized from aqueous ethanol to provide yellow crystals of 3-(4'-bromophenyl)-2-nitronaphtho-[1,2-b]furan, m.p. 230°-233° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04231965 |
| 出典データセット | uspto-grants-1980_11 |
| ORD ID | ord-8f0246653e0d4b4abe351e69b7395e98 |
| 出典メモ | uspto-grants-1980_11 |