化工社化工社 化学情報印刷レポート · 研究参考用
Ammonia → HCID 178508665、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ammonia | HCID 222 | — |
| 反応物 | 2,3-Dicyanonaphthalene | HCID 601270 | — |
| 反応物 | Sodium Methoxide | HCID 10942334 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | HCID 178508665 | HCID 178508665 | 66% |
反応手順
In 2.5 moles of 2,3-dicyanonaphthalene, 0.075 mole of sodium methoxide and 1 liter of methanol, an ammonia gas was flowed with a suitable flow rate for 40 minutes. Then, the reaction solution was refluxed with heating while flowing the ammonia gas for 4 hours. After cooling, the product was filtered, and recrystallized from a mixed solvent of methanol/ether to yield yellow 1,3-diiminobenz(f)isoindoline in 66% yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05428152 |
| 出典データセット | uspto-grants-1995_06 |
| ORD ID | ord-38e578938dce4dfbae253f92a8e8872b |
| 出典メモ | uspto-grants-1995_06 |