Ammonia → (3-Aminopropyl)triethoxysilane

HRID 224739

反応式

HRID 224739 の反応式
[NH3:1].[Cl:2][CH2:3][CH2:4][CH2:5][Si:6]([O:13][CH2:14][CH3:15])([O:10][CH2:11][CH3:12])[O:7][CH2:8][CH3:9]>>[Cl:2][CH2:3][CH2:4][CH2:5][Si:6]([O:13][CH2:14][CH3:15])([O:7][CH2:8][CH3:9])[O:10][CH2:11][CH3:12].[NH2:1][CH2:3][CH2:4][CH2:5][Si:6]([O:13][CH2:14][CH3:15])([O:10][CH2:11][CH3:12])[O:7][CH2:8][CH3:9]

参加物

4

反応物 2

HCID 222Ammonia2 回HCID 78771(3-Chloropropyl)triethoxysilane

生成物 2

HCID 13521(3-Aminopropyl)triethoxysilaneHCID 78771(3-Chloropropyl)triethoxysilane

実験手順

Into a ten-liter steel autoclave with stirrer, 3400 g (200 moles) of liquid ammonia was poured, and the reactor was sealed. Then the ammonia was heated to 75° C., causing a pressure of 36 bars to be established. After this temperature was reached, γ-chloropropyltriethoxysilane was fed in, with stirring at 183 rpm, for a period of one hour, in the amount of 2.67 moles; then stirring was continued for 8 hours at 75° C. Then the pressure was let off and the ammonia was removed. After the removal of ammonium chloride by filtration, the remaining raw product was purified by vacuum distillation. From the 642 grams of γ-chloropropyltriethoxysilane, 486 g of γ-aminopropyltriethoxysilane was obtained (82.4% of the theoretical yield) plus 98.3 g of byproducts (secondary and tertiary amines).

後処理

  1. customthe reactor was sealed
  2. stirringthen stirring
  3. waitwas continued for 8 hours at 75° C
  4. customthe ammonia was removed
  5. customAfter the removal of ammonium chloride
  6. filtrationby filtration
  7. distillationthe remaining raw product was purified by vacuum distillation

出典と根拠

ORDレコード
ord-be521702e17b4bb5967e091e186e04e9
出典データセット
uspto-grants-1980_11
特許番号
US04234502

関連ノート

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