関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Methyl Isobutyl Ketone | HCID 7909 | — |
| 反応物 | 3,7-Dimethylocta-2,6-Dienal | HCID 8843 | — |
| 触媒 | Zinc acetate (USP) | HCID 2724192 | — |
| 生成物 | 2,8,12-Trimethyl-5,7,11-tridecatrien-4-one | HCID 54329025 | 32.5% |
反応手順
Into a 2 liter autoclave are charged citral (152 grams), methyl isobutyl ketone (500 grams) and zinc acetate dihydrate (38 grams). The reaction mixture is heated at 160° C. for a period of 12 hours. After filtering the catalyst the organic layer is washed with 10% salt solution. Distillation yielding 76 grams (32% yield) of the product, B.P. 126°-141° C./1 mmHg.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04234518 |
|---|
| 出典データセット | uspto-grants-1980_11 |
|---|
| ORD ID | ord-7dab42019d5845d293961498223c3dbd |
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| 出典メモ | uspto-grants-1980_11 |
|---|
