Water → Diphenyltin dihydride
反応式
[H-].[Al+3].[Li+].[H-].[H-].[H-].[C:7]1([Sn:13](Cl)(Cl)[C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1.O>CCOCC>[C:14]1([SnH2:13][C:7]2[CH:8]=[CH:9][CH:10]=[CH:11][CH:12]=2)[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1参加物
5
実験手順
To an ice-cooled suspension of 0.76 g of lithium aluminum hydride in 15 ml of dry ether, was added 6.88 g of diphenyltin dichloride dissolved in 20 ml of dry ether. After stirring for 30 minutes, 20 ml of water was added to the resulted reaction mixture, and the ether layer was washed with icy water and dried over calcium chloride. The subsequent concentration under reduced pressure gave diphenyltin hydride.
後処理
- washthe ether layer was washed with icy water
- dry with materialdried over calcium chloride
- concentrationThe subsequent concentration under reduced pressure
出典と根拠
- ORDレコード
- ord-82037b4cc8384f17a8e6aa4b7ff94744
- 出典データセット
- uspto-grants-1991_08
- 特許番号
- US05041641
反応ノート
読み込み中…