Methanol → Methyl Benzoate

HRID 224949

反応式

HRID 224949 の反応式
C(C#N)(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:11](Cl)(=[O:18])C1C=CC=CC=1.S(=O)(=O)(O)O.[CH3:25][OH:26]>>[C:25]([O:18][CH3:11])(=[O:26])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

参加物

5

反応物 4

HCID 887MethanolHCID 1118Sulfuric AcidHCID 7412Benzoyl chlorideHCID 11953Phenylglyoxylonitrile

生成物 1

HCID 7150Methyl Benzoate

実験手順

For example, when pure benzoyl cyanide (i.e., containing essentially no halide ion or halide ion source, such as benzoyl chloride) is reacted with concentrated sulfuric acid and then esterified by further reaction with methanol, the cyano group is cleaved and methyl benzoate is formed as follows: ##STR2##

出典と根拠

ORDレコード
ord-3210b225ed214befa775d9f51e527f56
出典データセット
uspto-grants-1980_11
特許番号
US04234739

関連ノート

読み込み中…