4-tert-Butylbenzaldehyde → 4-tert-Butyltoluene

HRID 225011

反応式

HRID 225011 の反応式
[C:1]([C:5]1[CH:12]=[CH:11][C:8]([CH:9]=O)=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].C(OCC1C=CC(C(C)(C)C)=CC=1)(=O)C>>[C:1]([C:5]1[CH:6]=[CH:7][C:8]([CH3:9])=[CH:11][CH:12]=1)([CH3:4])([CH3:3])[CH3:2]

参加物

3

反応物 2

HCID 703244-tert-ButylbenzaldehydeHCID 105421Benzenemethanol, 4-(1,1-dimethylethyl)-, 1-acetate

生成物 1

HCID 73904-tert-Butyltoluene収率 83.3%

実験手順

If the material discharged from the electrolysis is worked up similarly to Example 1, 284.8 g of p-tert.-butylbenzaldehyde and 295.3 g of p-tert.-butylbenzyl acetate are obtained in addition to 25.2 g of unconverted p-tert.-butyltoluene. This corresponds to a yield of 83.3% and a current efficiency of 58.2%. The p-tert.-butylbenzaldehyde is separated from the p-tert.-butylbenzyl acetate by the method described in Example 1.

出典と根拠

ORDレコード
ord-5cac8f11e5494aa1bdf787d75a261d71
出典データセット
uspto-grants-1980_11
特許番号
US04235683

関連ノート

読み込み中…