Morpholine → 4-(4-Benzyloxy-3-nitro-phenyl)-morpholine
反応式
[NH:1]1[CH2:6][CH2:5][O:4][CH2:3][CH2:2]1.[CH2:7]([O:14][C:15]1[CH:20]=[CH:19][C:18](Br)=[CH:17][C:16]=1[N+:22]([O-:24])=[O:23])[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1.COC1C=CC(N2CCOCC2)=CC=1[N+]([O-])=O>>[CH2:7]([O:14][C:15]1[CH:20]=[CH:19][C:18]([N:1]2[CH2:6][CH2:5][O:4][CH2:3][CH2:2]2)=[CH:17][C:16]=1[N+:22]([O-:24])=[O:23])[C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1参加物
4
実験手順
The title compound was prepared using morpholine and 1-benzyloxy-4-bromo-2-nitro-benzene (prepared from 4-bromo-2-nitro-anisol and benzyl bromide) using the general method of example “4-(4-methoxy-3-nitro-phenyl)-morpholine” as yellow solid (58%), MS: m/e=315(M+H+).
出典と根拠
- ORDレコード
- ord-a54904de9fcd4f69a09d0d0542f6de1d
- 出典データセット
- uspto-grants-2008_01