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Vinylene carbonate → cis-2-Chloro-9,10-dihydro-9,10-ethanoanthracene-11,12-diol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Vinylene carbonate | HCID 13385 | — |
| 反応物 | 2-Chloroanthracene | HCID 28308 | — |
| 生成物 | cis-2-Chloro-9,10-dihydro-9,10-ethanoanthracene-11,12-diol | HCID 53990653 | — |
反応手順
A solution of 15.0 g. of 2-chloroanthracene in 60.8 g. of vinylene carbonate is refluxed for 20 hours and then vacuum distilled. The residue is recrystallized from methylene chloride-methanol giving cis-2-chloro-9,10-dihydro-9,10-ethanoanthracene-11,12-diol, cyclic carbonate as gray crystals, m.p. 200°-230° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04235996 |
| 出典データセット | uspto-grants-1980_11 |
| ORD ID | ord-9c27bbf0ed2f4ea09aadab3a236398a7 |
| 出典メモ | uspto-grants-1980_11 |